The events of one woman's life following her divorce after years of marriage to a Hollywood studio executive. Based on the best-selling novel by Gigi Levangie Grazer.
The Starter Wife (Season 2)
The Forty-Year-Old Virgin Queen (Episode 1)
Air date: 2008-10-10
Runtime: 60 min
Overview: Molly hopes to revitalize her career by using material from her diary in a writing workshop. Elsewhere, Joan wrangles an abrasive ex-sex symbol with her job at a rehab facility. Also, Rodney develops a crush on a client, a macho action star.
The Diary of a Mad Ex-Housewife (Episode 2)
Air date: 2008-10-10
Runtime: 60 min
Overview: Molly's journal is stolen during a party in Zach's house and the result can be a disaster. Rodney has a surprise about his new client.
Remains of the Snow Day (Episode 3)
Air date: 2008-10-17
Runtime: 60 min
Overview: Molly has been recognized as the Hollywood Ex-wife by a gossip blogger, causing her to hide at the Destinies. Elsewhere, Rodney explains his relationship with Felix to Molly, and Joan starts an affair.
Mollywood (Episode 4)
Air date: 2008-10-24
Runtime: 60 min
Overview: Molly meets with a Hollywood agent, Eve's husband, and is thinking of adding a P.I. element to her book. Elsewhere, Devon has Liz feeling suspicious; Felix and Rodney get into a fight; and Joan juggles both her friendship with Robin and a relationship with David.
Das Booty Call (Episode 5)
Air date: 2008-10-31
Runtime: 60 min
Overview: Just as Molly's relationship with Zach progresses, Lou shows up. Liz's jealousy makes Devon feel distracted. David is persuaded by Joan into appearing in David's movie.
The Ex-Files (Episode 6)
Air date: 2008-11-07
Runtime: 60 min
Overview: Kenny's threats to derail Molly's movie has her going to surprising measures to protect it.
The French Disconnection (Episode 7)
Air date: 2008-11-14
Runtime: 60 min
Overview: A secret uncovered about Zach's past fills Molly with misgivings. Elsewhere, Molly thinks Lou's fiancee is holding a secret, and a surprise decision is made by Felix.
Look Who's Stalking (Episode 8)
Air date: 2008-11-21
Runtime: 60 min
Overview: Molly and Zack reevaluate their relationship after a confrontation with Molly's stalker.
Her Old Man and the Sea (Episode 9)
Air date: 2008-12-05
Runtime: 60 min
Overview: With the police investigating Pappy's disappearance, Joan makes her return to Los Angeles.
Woman Over the Influence (Episode 10)
Air date: 2008-12-12
Runtime: 60 min
Overview: The season finale finds Molly assessing her future with Zach through Lou's wedding ceremony. Elsewhere, Joan reveals a confession, Rodney's relationship changes, and Liz's life becomes turbulent.

Seasons
Episodes 6
Episodes 10